Talk:Radical anion

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Rename and reorg? edit

Latest comment: 3 years ago1 comment1 person in discussion

I was thinking of moving and reorganizing this thing into an article on pi-radical anions. Those species are widely used so the resulting articla might be well consulted. Some possible content, borrowed from sodium nathphenide:

Sodium acenaphthalenide is milder by about 0.75 V, reflecting the milder reduction potential of polycyclic aromatic compounds.
Lithium biphenyl is a THF-soluble species related to sodium naphthalenide except that it is a poorer ligand.^[1]
Sodium 1-methylnaphthalenide is more soluble than sodium naphthalenide, which is useful for low-temperature reductions.^[2]
Sodium pyrene.^[3]

The rest of the content in this article superficially appears to be too generic. Alternative ideas and objections are welcome.--Smokefoot (talk) 17:33, 22 March 2021 (UTC)Reply

References

^ Rieke, Reuben D.; Wu, Tse-Chong & Rieke, Loretta I. (1995). "Highly Reactive Calcium for the Preparation of Organocalcium Reagents: 1-Adamantyl Calcium Halides and Their Addition to Ketones: 1-(1-Adamantyl)cyclohexanol". Org. Synth. 72: 147. doi:10.15227/orgsyn.072.0147.
^ Liu, X.; Ellis, J. E. (2004). "Hexacarbonylvanadate(1−) and Hexacarbonylvanadium(0)". Inorg. Synth. 34: 96–103. doi:10.1002/0471653683.ch3. ISBN 0-471-64750-0.
^ Kucera, Benjamin E.; Jilek, Robert E.; Brennessel, William W.; Ellis, John E. (2014). "Bis(pyrene)metal complexes of vanadium, niobium and titanium: Isolable homoleptic pyrene complexes of transition metals". Acta Crystallographica Section C Structural Chemistry. 70 (8): 749–753. doi:10.1107/S2053229614015290. PMID 25093352.

Add topic

[1] Rieke, Reuben D.; Wu, Tse-Chong & Rieke, Loretta I. (1995). "Highly Reactive Calcium for the Preparation of Organocalcium Reagents: 1-Adamantyl Calcium Halides and Their Addition to Ketones: 1-(1-Adamantyl)cyclohexanol". Org. Synth. 72: 147. doi:10.15227/orgsyn.072.0147.

[2] Liu, X.; Ellis, J. E. (2004). "Hexacarbonylvanadate(1−) and Hexacarbonylvanadium(0)". Inorg. Synth. 34: 96–103. doi:10.1002/0471653683.ch3. ISBN 0-471-64750-0.

[3] Kucera, Benjamin E.; Jilek, Robert E.; Brennessel, William W.; Ellis, John E. (2014). "Bis(pyrene)metal complexes of vanadium, niobium and titanium: Isolable homoleptic pyrene complexes of transition metals". Acta Crystallographica Section C Structural Chemistry. 70 (8): 749–753. doi:10.1107/S2053229614015290. PMID 25093352.

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