Talk:Haloform reaction

Latest comment: 15 years ago by Stone
  • Reynold C. Fuson and Benton A. Bull (1934). "The Haloform Reaction". Chemical Reviews. 15 (3): 275–309. doi:10.1021/cr60052a001.
  • SERULLAS Ann. chim. 20, 165 (1822);
  • LIEBEN: Ann. Spl. Bd. 7, 218 (1870).
  • LIEBEN: Ann. Spl. Bd. 7, 377 (1870).--Stone (talk) 11:08, 1 March 2009 (UTC)Reply

Mechanism suspect

edit

I seriously doubt that the mechanism of I2 oxidation of secondary alcohols involves a ternary encounter, as depicted. Besides, no reference is provided. Much more likely in my mind is the α-deprotonation of an R-OI intermediate.

Pgpotvin (talk)