Antimonide iodides or iodide antimonides are compounds containing anions composed of iodide (I−) and antimonide (Sb3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the antimonide chlorides, antimonide iodides, phosphide iodides, and arsenide iodides.
List edit
Go straight to Antimonide iodide
Thioantimonate iodides edit
| formula | system | space group | unit cell Å | volume | density | comment | ref |
|---|---|---|---|---|---|---|---|
| (LiI)2Li3SbS3 | orthorhombic | Pnnm | a = 10.436, b = 13.509, c = 7.530 Z = 4 | 1061.6 | pale yellow; air+water sensitive | [1] | |
| (CuI)2Cu3SbS3 | orthorhombic | Pnnm | a = 10.488, b = 12.619, c = 7.316 Z = 4 | 968.2 | red orange | [2] | |
| (AgI)2Ag3SbS3 | orthorhombic | Pnnm | a = 10.9674, b = 13.520, c = 7.7460, Z = 4 | 1156.3 | pale yellow | [3] | |
| Sn2SbS2I3 | [4] | ||||||
| Pb2SbS2I3 | orthorhombic | Cmcm | a = 4.3262, b = 14.181, c = 16.556 Z=4 | 1017.7 | room temperature | [4] |
Selenoantimonate iodides edit
| formula | system | space group | unit cell Å | volume | density | comment | ref |
|---|---|---|---|---|---|---|---|
| MnSbSe2I | monoclinic | C2/m | a = 13.319 b = 4.0359 c = 10.105 β = 91.27 | [5] | |||
| [3] | |||||||
| Sn2SbSe2I3 | [4] |
References edit
- ^ Pfitzner, Arno; Preitschaft, Christian; Rau, Franz (January 2004). "(LiI)2Li3SbS3: A mixed Alkali Metal Halide Thioantimonate with a novel Tetrahedron Network". Zeitschrift für anorganische und allgemeine Chemie (in German). 630 (1): 75–79. doi:10.1002/zaac.200300292. ISSN 0044-2313.
- ^ Pfitzner, Arno (December 1997). "(CuI)2Cu3SbS3: Copper Iodide as Solid Solvent for Thiometalate ions". Chemistry - A European Journal (in German). 3 (12): 2032–2038. doi:10.1002/chem.19970031218.
- ^ a b Nilges, Tom; Reiser, Sara; Hong, Jung Hoon; Gaudin, Etienne; Pfitzner, Arno (2002). "Preparation, structural, Raman and impedance spectroscopic characterisation of the silver ion conductor (AgI) 2 Ag 3 SbS 3". Phys. Chem. Chem. Phys. 4 (23): 5888–5894. doi:10.1039/B203556A. ISSN 1463-9076.
- ^ a b c Doussier, Charlotte; Moëlo, Yves; Léone, Philippe; Meerschaut, Alain; Evain, Michel (September 2007). "Crystal structure of Pb2SbS2I3, and re-examination of the crystal chemistry within the group of (Pb/Sn/Sb) chalcogeno-iodides". Solid State Sciences. 9 (9): 792–803. Bibcode:2007SSSci...9..792D. doi:10.1016/j.solidstatesciences.2007.07.003.
- ^ Tougait, Olivier; Ibers, James A.; Mar, Arthur (2003-08-15). "Manganese antimony diselenide iodide, MnSbSe 2 I". Acta Crystallographica Section C Crystal Structure Communications. 59 (8): i77–i78. doi:10.1107/S0108270103014082. ISSN 0108-2701. PMID 12909744.