User:Crazyjimbo/Draft of Finite potential well

The finite potential well (also known as the finite square well) is a simple problem from quantum mechanics. It is an extension of the infinite potential well, in which a particle is confined to a box, but one which has finite - not infinite - potential walls. This means unlike the infinite potential well, there is a probability associated with the particle being found outside of the box. The quantum mechanical interpretation is unlike the classical interpretation, where if the total energy of the particle is less than potential energy barrier of the walls it cannot be found outside the box. In the quantum interpretation, there is a non-zero probability of the particle being outside the box even when the energy of the particle is less than the potential energy barrier of the walls (because of quantum tunnelling).

1-Dimensional Finite Potential Well

Finite Square Well Potential

For the 1-dimensional case on the x-axis, the potential of the finite square well is

V(x)={\begin{cases}-V_{0},&{\textrm {for}}-a\leq x\leq a,\\0,&{\textrm {for}}|x|>a,\end{cases}}

where a and V₀ are positive constants. This potential admits both bound states and scattering states depending on whether E > 0 or E < 0.^[1]

Bound States

Bound states occur when E < 0. To solve the Schrödinger equation for this potential, the areas to the left of the well, within the well and to right of the well must be considered separately.

Left of the Well

To the left of the well, where x < -a, the potential is zero and the time independent Schrödinger equation reduces to

-{\frac {\hbar }{2m}}{\frac {d^{2}\psi }{dx^{2}}}=E\psi .\qquad {\text{(1)}}

Setting

k={\frac {\sqrt {-2mE}}{\hbar }},

where k is positive since E < 0, the time independent Schrödinger equation can be written as

{\frac {d^{2}\psi }{dx^{2}}}=k^{2}\psi .

This is a well studied differential equation and eigenvalue problem with a general solution of

\psi (x)=Ae^{-kx}+Be^{kx}

where A and B can be any complex numbers, and k can be any real number.

If this solution is to represent a real world particle it must be normalisable and since e^-kx goes to infinity as x goes to infinity in the negative direction, B must be zero. The physically admissible solution to equation (1) is then

\psi (x)=Ae^{kx}

Inside the Well

When -a < x < a, the potential is given by V(x) = V₀ and time independent Schrödinger equation is

-{\frac {\hbar }{2m}}{\frac {d^{2}\psi }{dx^{2}}}-V_{0}\psi =E\psi .\qquad {\text{(2)}}

Setting

k={\frac {\sqrt {2m(E+V_{0})}}{\hbar }},

the time independent Schrödinger equation can be written as

{\frac {d^{2}\psi }{dx^{2}}}=-l^{2}\psi .

Note that l is real since E > V_min = -V₀^{[citation needed]} and thus E + V₀ > 0.

This equation has a general solution of

\psi (x)=C\sin(lx)+D\cos(lx),

where C and D can be any complex numbers.

Right of the Well

By similar treatment to left of the well, when x > a, the physically admissible solution to equation (1) is

\psi (x)=Fe^{-kx}

Solution

The potential is an even function so the full solutions are either even or odd^{[citation needed]}. For the even solutions, the solution inside the well will be $\psi (x)=D\cos(lx)$ and the full solution given by:

\psi (x)={\begin{cases}Fe^{-kx},&{\textrm {for}}x>a,\\D\cos(lx),&{\textrm {for}}-a\leq x\leq a,\\Fe^{kx},&{\textrm {for}}x<-a,\end{cases}}

$\psi$ and ${\frac {d\psi }{dx}}$ are required to be continuous at x = a and x = -a and so

Fe^{-ka}=Dcos(la),

and

-kFe^{-ka}=-lDsin(la).

Dividing, gives

k=l\tan(la).

This equation gives a condition on E but cannot be solved analytically for exact solutions.

Similar analysis gives the odd solution as

\psi (x)={\begin{cases}Fe^{-kx},&{\textrm {for}}x>a,\\D\sin(lx),&{\textrm {for}}-a\leq x\leq a,\\Fe^{kx},&{\textrm {for}}x<-a,\end{cases}}

with

l=-k\tan(la).

References

^ Griffiths, David J. (2005). Introduction to Quantum Mechanics (2^nd ed. ed.). Prentice Hall. ISBN 0-13-111892-7. {{cite book}}: |edition= has extra text (help)

Category:Quantum mechanics

[1] Griffiths, David J. (2005). Introduction to Quantum Mechanics (2^nd ed. ed.). Prentice Hall. ISBN 0-13-111892-7. {{cite book}}: |edition= has extra text (help)

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