Talk:Carbon diselenide

Latest comment: 10 years ago by Smokefoot in topic Odor

Bent molecule? edit

The article states that CSe2, like CS2, is a bent molecule.

CS2 is linear, not bent, and CSe2 should likewise be linear: Se=C=Se.

What's going on?

Ben (talk) 04:14, 28 February 2008 (UTC)Reply

The article is from a non professional! So if you know it better change it!

I'm no pro either, that's why I was checking.

Ben (talk) 17:13, 2 March 2008 (UTC)Reply

You are pro enough, according to your edits!--Stone (talk) 15:17, 3 March 2008 (UTC)Reply

References edit

  • Chemistry of Carbon Diselenide. II Alkylation of Substituted Selenoureas by J. S. WARNER AND T. F. PAGE, JR.
  • Poly(carbon dise1enide)by BY A. J. BROWN ASD E. WHALLEY
  • D. J. G. Ives, R. W. Pittman and W. Wardlaw (1947). "The preparation, properties, and chlorination products of carbon diselenide". J. Chem. Soc.,: 1080–1083, . doi:10.1039/JR9470001080.{{cite journal}}: CS1 maint: extra punctuation (link)
  • Chemistry of Carbon Diselenide. I. Reactions with Primary Amines by J . S . WARXER
  • Y. Okamoto; Z. Iqbal; R. H. Baughman (1988). "The Structure and Properties of Poly(Carbon Dichalcogenides)". Journal of Macromolecular Science. 25 (5–7): 799–810. doi:10.1080/00222338808053399.{{cite journal}}: CS1 maint: multiple names: authors list (link)

Odor edit

Is described, if CSe2 itself is having the very pungent odor, or if the odor is produced by impurities and decomposition products? The analogous CS2 is described being only vile-smelling if it contains impurities, e.g. carbonyl sulfide. --79.243.236.94 (talk) 16:33, 9 September 2013 (UTC)Reply

Good point. I think that the fear of playing with CSe2 prevented a thorough investigation of the exact source of the odor. BTW, my recollection is that COS is not the bad odor in CS2, but other things. --Smokefoot (talk) 22:44, 9 September 2013 (UTC)Reply