Samarium(III) oxyiodide

Samarium(III) oxyiodide is an inorganic compound with the chemical formula SmOI. It can be obtained by reacting samarium(II) iodide with dry oxygen.[2] It is oxidized when heated to 335 °C in air, and starts to generate nSmOI·Sm2O3 (n is 7, 4, 2 respectively) at 460 °C, 560 °C, and 640 °C, and completely transforms at 885 °C for samarium oxide.[3] It can catalyze the rearrangement of propylene oxide derivatives to methyl ketones.[2] It reacts with samarium(III) iodide, sodium iodide, and sodium at 903 K in a tantalum container to obtain black Sm4OI6.[4]

Samarium(III) oxyiodide
Names
Other names
Samarium iodide oxide
Identifiers
3D model (JSmol)
  • InChI=1S/HI.O.Sm/h1H;;/q;-2;+3/p-1
    Key: CGXYQWRVSQQLMC-UHFFFAOYSA-M
  • [Sm+3].[O-2].[I-]
Properties
IOSm
Molar mass 293.26 g·mol−1
Appearance light milky yellow solid[1]
Related compounds
Other anions
samarium oxysulfide
samarium oxychloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

References

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  1. ^ 刘书珍; 李有谟; 李继文; 陈明玉. 稀土碘氧化物的制备和X-射线分析. 应用化学. 1988. 5 (3): 64-66.
  2. ^ a b J. Prandi, J.L. Namy, G. Menoret, H.B. Kagan (1985-04-01). "Selective catalyzed-rearrangement of terminal epoxides to methyl ketones". Journal of Organometallic Chemistry. 285 (1–3): 449–460. doi:10.1016/0022-328X(85)87389-7. Retrieved 2023-03-16.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  3. ^ J. P. K. Hölsä (1982-10-01). "Thermal stabilities of selected rare earth oxyiodides". Journal of Thermal Analysis. 25 (1): 127–133. doi:10.1007/BF01913061. ISSN 0368-4466. S2CID 93183720. Retrieved 2023-03-16.
  4. ^ Stefanie Hammerich, Ingo Pantenburg, Gerd Meyer (2005-11-15). "Tetrasamarium(II) oxide hexaiodide, Sm 4 OI 6". Acta Crystallographica Section E: Structure Reports Online. 61 (11): i234–i236. Bibcode:2005AcCrE..61I.234H. doi:10.1107/S1600536805031934. ISSN 1600-5368. Retrieved 2023-03-16.{{cite journal}}: CS1 maint: multiple names: authors list (link)

External reading

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