o-Toluic acid, also 2-methylbenzoic acid, is an aromatic carboxylic acid, with formula (CH3)C6H4(COOH). It is an isomer of p-toluic acid and m-toluic acid. When purified and recrystallized, o-toluic acid forms needle-shaped crystals. o-Toluic acid was first noticed by Sir William Ramsay, credited discoverer of the noble gases and winner of the 1904 Nobel Prize in Chemistry.
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Names | |||
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Preferred IUPAC name
2-Methylbenzoic acid | |||
Other names
ortho-toluic acid
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Identifiers | |||
3D model (JSmol)
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ChEBI | |||
ChEMBL | |||
ChemSpider | |||
ECHA InfoCard | 100.003.896 | ||
KEGG | |||
PubChem CID
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UNII | |||
CompTox Dashboard (EPA)
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Properties | |||
C8H8O2 | |||
Molar mass | 136.2 g/mol | ||
Density | 1.06 g/cm3 | ||
Melting point | 104 to 105 °C (219 to 221 °F; 377 to 378 K) | ||
Boiling point | 259 °C (498 °F; 532 K) | ||
-80.83·10−6 cm3/mol | |||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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o-Toluic acid is prepared by oxidation of o-xylene with nitric acid.[2]
References
edit- ^ O-TOLUIC ACID - Compound Summary, PubChem.
- ^ Harold E. Zaugg; Richard T. Rapala (1947). "o-Toluic Acid". Org. Synth. 27: 84. doi:10.15227/orgsyn.027.0084.