Lithium hexafluoroantimonate

Lithium hexafluoroantimonate is an inorganic chemical compound with the chemical formula LiSbF6.[1][2][3]

Lithium hexafluoroantimonate
Names
IUPAC name
lithium;hexafluoroantimony(1-)
Other names
Lithium hexafluoroantimonate(V)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.196.093 Edit this at Wikidata
EC Number
  • 670-363-3
  • InChI=1S/6FH.Li.Sb/h6*1H;;/q;;;;;;+1;+5/p-6
    Key: YVBBFYDVCPCHHG-UHFFFAOYSA-H
  • [Li+].F[Sb-](F)(F)(F)(F)F
Properties
NaSbF6
Appearance White to off-white powder
soluble
Hazards
GHS labelling:
GHS07: Exclamation markGHS09: Environmental hazard
Warning
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Physical properties

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The compound crystallizes in the rhombohedral space group R3 with the lattice constants a = 5.43 Å, α = 56° 58', Z = 1. The structure corresponds to that of rhombohedral distorted NaSbF6 type.[4][5]

References

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  1. ^ "Lithium hexafluoroantimonate(V)". Sigma Aldrich. Retrieved 1 July 2024.
  2. ^ Haynes, William M. (9 June 2015). CRC Handbook of Chemistry and Physics, 96th Edition. CRC Press. p. 4-72. ISBN 978-1-4822-6097-7. Retrieved 1 July 2024.
  3. ^ Manthiram, Arumugam (March 2009). Rechargeable Lithium and Lithium Ion Batteries. The Electrochemical Society. p. 157. ISBN 978-1-56677-704-9. Retrieved 1 July 2024.
  4. ^ Burns, J. H. (10 November 1962). "The crystal structure of lithium fluoroantimonate(V)". Acta Crystallographica. 15 (11): 1098–1101. doi:10.1107/S0365110X62002935. ISSN 0365-110X. Retrieved 1 July 2024.
  5. ^ Donnay, Joseph Désiré Hubert (1978). Crystal Data: Inorganic compounds 1967-1969. National Bureau of Standards. p. H/R-188. Retrieved 1 July 2024.