This page provides supplementary chemical data on n-butane.
Material Safety Data Sheet edit
The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source such as eChemPortal, and follow its directions.
Structure and properties edit
Structure and properties | |
---|---|
Index of refraction, nD | 1.3326 at 20 °C[1] |
Dielectric constant, εr | 1.7697 ε0 at 23 °C[2] |
Symmetry group | C2h |
Magnetic susceptibility | ? |
Surface tension | 12.46 dyn/cm at 20 °C P ≈ 225 kPa |
Thermodynamic properties edit
Phase behavior | |
---|---|
Density (liquid) 0 °C | 600 kg/m³ |
Density (saturated vapor) 1 atm, -0.5 °C | 2.6 kg/m³ |
Triple point | 134.6 K (–138.5 °C), 0.7 Pa |
Critical point | 425.1 K (152.0 °C), 3796.0 kPa |
Std enthalpy change of fusion, ΔfusH |
4.66 kJ/mol |
Std entropy change of fusion, ΔfusS |
34.56 J/(mol·K) |
Std enthalpy change of vaporization, ΔvapH |
22.44 kJ/mol |
Std entropy change of vaporization, ΔvapS |
82.30 J/(mol·K) |
Solid properties | |
Std enthalpy change of formation, ΔfH |
? kJ/mol |
Standard molar entropy, S |
? J/(mol K) |
Heat capacity, cp | ? J/(mol K) |
Liquid properties | |
Std enthalpy change of formation, ΔfH |
-147.6 kJ/mol |
Standard molar entropy, S |
229.7 J/(mol K) |
Heat capacity, cp | 132.42 J/(mol K) –262 °C to –3 °C |
Gas properties | |
Std enthalpy change of formation, ΔfH |
–124.7 kJ/mol |
Standard molar entropy, S |
310.23 J/(mol K) |
Enthalpy of combustion, ΔcH |
–2877.5 kJ/mol |
Heat capacity, cp | 98.49 J/(mol K) at 25 °C |
n-butane van der Waals' constants[3] |
a = 1466.2 L2 kPa/mol2 b = 0.1226 liter per mole |
Vapor pressure of liquid edit
P in mm Hg | 1 | 10 | 40 | 100 | 400 | 760 | 1520 | 3800 | 7600 | 15200 | 30400 | 45600 | |
T in °C | –101.5 | –77.8 | –59.1 | –44.2 | –16.3 | –0.5 | 18.8 | 50.0 | 79.5 | 116.0 | — | — |
n-Butane: Table data obtained from CRC Handbook of Chemistry and Physics 44th ed.
Spectral data edit
UV-Vis | |
---|---|
λmax | ? nm |
Extinction coefficient, ε | ? |
IR | |
Major absorption bands | ? cm−1 |
NMR | |
Proton NMR | |
Carbon-13 NMR | |
Other NMR data | |
MS | |
Masses of main fragments |
References edit
- ^ CRC Handbook of Chemistry and Physics 85th ed, pp 202
- ^ CRC Handbook of Chemistry and Physics 85th ed, pp 1148
- ^ Lange's Handbook of Chemistry 10th ed, pp. 1522–1524
- ^ Zivenko, Oleksiy (2019). "LPG Accounting Specificity During ITS Storage and Transportation". Measuring Equipment and Metrology. 80 (3): 21–27. doi:10.23939/istcmtm2019.03.021. ISSN 0368-6418. S2CID 211776025.
- "Multifunctional Green Alternative: Propane and Butane (properties)". Seminck. Archived from the original on 28 September 2007. Retrieved 1 May 2007.
This box:
- Except where noted otherwise, data relate to Standard temperature and pressure.
- Reliability of data general note.