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Isotopes of neptunium

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Neptunium (93Np) is usually considered an artificial element, although trace quantities are found in nature, so a standard atomic weight cannot be given. Like all trace or artificial elements, it has no stable isotopes. The first isotope to be synthesized and identified was 239Np in 1940, produced by bombarding 238
U
 with neutrons to produce 239
U
, which then underwent beta decay to 239
Np
.

Isotopes of neptunium (93Np)
Main isotopes[1] Decay
abun­dance half-life (t1/2) mode pro­duct
235Np synth 396.1 d α 231Pa
ε 235U
236Np synth 1.54×105 y ε 236U
β− 236Pu
α 232Pa
237Np trace 2.144×106 y α 233Pa
239Np trace 2.356 d β− 239Pu

Trace quantities are found in nature from neutron capture reactions by uranium atoms, a fact not discovered until 1951.[2]

Twenty-five neptunium radioisotopes have been characterized, with the most stable being 237
Np
 with a half-life of 2.14 million years, 236
Np
 with a half-life of 154,000 years, and 235
Np
 with a half-life of 396.1 days. All of the remaining radioactive isotopes have half-lives that are less than 4.5 days, and the majority of these have half-lives that are less than 50 minutes. This element also has five meta states, with the most stable being 236m
Np
 (t1/2 22.5 hours).

The isotopes of neptunium range from 219
Np
 to 244
Np
, though the intermediate isotope 221
Np
 has not yet been observed. The primary decay mode before the most stable isotope, 237
Np
, is electron capture (with a good deal of alpha emission), and the primary mode after is beta emission. The primary decay products before 237
Np
 are isotopes of uranium and protactinium, and the primary products after are isotopes of plutonium. Neptunium is the heaviest element for which the location of the proton drip line is known; the lightest bound isotope is 220Np.[3]

List of isotopes

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Nuclide
[n 1] 		Z N Isotopic mass (Da)[4]
[n 2][n 3] 		Half-life
 Decay
mode
[n 4] 		Daughter
isotope
[n 5] 		Spin and
parity
[n 6][n 7] 		Isotopic
abundance
Excitation energy[n 7]
219
Np
[5][n 8] 		93 126 219.03162(9) 0.15+0.72
−0.07 ms 		α 215Pa (9/2−)
220
Np
[3] 		93 127 220.03254(21)# 25+14
−7 μs 		α 216Pa 1−#
222
Np
[6] 		93 129 380+260
−110 ns 		α 218Pa 1-#
223
Np
[7] 		93 130 223.03285(21)# 2.15+100
−52 μs 		α 219Pa 9/2−
224
Np
[8] 		93 131 224.03422(21)# 38+26
−11 μs 		α (83%) 220m1Pa 1−#
α (17%) 220m2Pa
225
Np
 		93 132 225.03391(8) 6(5) ms α 221Pa 9/2−#
226
Np
 		93 133 226.03515(10)# 35(10) ms α 222Pa
227
Np
 		93 134 227.03496(8) 510(60) ms α (99.95%) 223Pa 5/2−#
β+ (.05%) 227U
228
Np
 		93 135 228.03618(21)# 61.4(14) s β+ (59%) 228U
α (41%) 224Pa
β+, SF (.012%) (various)
229
Np
 		93 136 229.03626(9) 4.0(2) min α (51%) 225Pa 5/2+#
β+ (49%) 229U
230
Np
 		93 137 230.03783(6) 4.6(3) min β+ (97%) 230U
α (3%) 226Pa
231
Np
 		93 138 231.03825(5) 48.8(2) min β+ (98%) 231U (5/2)(+#)
α (2%) 227Pa
232
Np
 		93 139 232.04011(11)# 14.7(3) min β+ (99.99%) 232U (4+)
α (.003%) 228Pa
233
Np
 		93 140 233.04074(5) 36.2(1) min β+ (99.99%) 233U (5/2+)
α (.001%) 229Pa
234
Np
 		93 141 234.042895(9) 4.4(1) d β+ 234U (0+)
234m
Np
 		~9 min[9] IT 234Np 5+
EC 234U
235
Np
 		93 142 235.0440633(21) 396.1(12) d EC 235U 5/2+
α (.0026%) 231Pa
236
Np
[n 9] 		93 143 236.04657(5) 1.54(6)×105 y EC (87.3%) 236U (6−)
β− (12.5%) 236Pu
α (.16%) 232Pa
236m
Np
 		60(50) keV 22.5(4) h EC (52%) 236U 1
β− (48%) 236Pu
237
Np
[n 10] 		93 144 237.0481734(20) 2.144(7)×106 y α 233Pa 5/2+ Trace[n 11]
SF (2×10−10%) (various)
CD (4×10−12%) 207Tl
30Mg
238
Np
 		93 145 238.0509464(20) 2.117(2) d β− 238Pu 2+
238m
Np
 		2300(200)# keV 112(39) ns
239
Np
 		93 146 239.0529390(22) 2.356(3) d β− 239Pu 5/2+ Trace[n 11]
240
Np
 		93 147 240.056162(16) 61.9(2) min β− 240Pu (5+) Trace[n 12]
240m
Np
 		20(15) keV 7.22(2) min β− (99.89%) 240Pu 1(+)
IT (.11%) 240Np
241
Np
 		93 148 241.058349(33)[10] 13.9(2) min β− 241Pu (5/2+)
242
Np
 		93 149 242.061738(87)[10] 2.2(2) min β− 242Pu (1+)
242m
Np
 		0(50)# keV 5.5(1) min 6+#
243
Np
 		93 150 243.06428(3)# 1.85(15) min β− 243Pu (5/2−)
244
Np
 		93 151 244.06785(32)# 2.29(16) min β− 244Pu (7−)
This table header & footer:
  1. ^ mNp – Excited nuclear isomer.
  2. ^ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. ^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. ^ Modes of decay:
    CD: Cluster decay
    EC: Electron capture
    IT: Isomeric transition
    SF: Spontaneous fission
  5. ^ Bold italics symbol as daughter – Daughter product is nearly stable.
  6. ^ ( ) spin value – Indicates spin with weak assignment arguments.
  7. ^ a b # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  8. ^ Heaviest known nucleus, as of 2019, that is beyond the proton drip line.
  9. ^ Fissile nuclide
  10. ^ Most common nuclide
  11. ^ a b Produced by neutron capture in uranium ore
  12. ^ Intermediate decay product of 244Pu

Actinides vs fission products

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Actinides and fission products by half-life
Actinides[11] by decay chain Half-life
range (a) 		Fission products of 235U by yield[12]
4n 4n + 1 4n + 2 4n + 3 4.5–7% 0.04–1.25% <0.001%
228Ra№ 4–6 a 155Euþ
248Bk[13] > 9 a
244Cmƒ 241Puƒ 250Cf 227Ac№ 10–29 a 90Sr 85Kr 113mCdþ
232Uƒ 238Puƒ 243Cmƒ 29–97 a 137Cs 151Smþ 121mSn
249Cfƒ 242mAmƒ 141–351 a

No fission products have a half-life
in the range of 100 a–210 ka ...

241Amƒ 251Cfƒ[14] 430–900 a
226Ra№ 247Bk 1.3–1.6 ka
240Pu 229Th 246Cmƒ 243Amƒ 4.7–7.4 ka
245Cmƒ 250Cm 8.3–8.5 ka
239Puƒ 24.1 ka
230Th№ 231Pa№ 32–76 ka
236Npƒ 233Uƒ 234U№ 150–250 ka 99Tc₡ 126Sn
248Cm 242Pu 327–375 ka 79Se₡
1.33 Ma 135Cs₡
237Npƒ 1.61–6.5 Ma 93Zr 107Pd
236U 247Cmƒ 15–24 Ma 129I₡
244Pu 80 Ma

... nor beyond 15.7 Ma[15]

232Th№ 238U№ 235Uƒ№ 0.7–14.1 Ga

Notable isotopes

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Neptunium-235

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Neptunium-235 has 142 neutrons and a half-life of 396.1 days. This isotope decays by:

This isotope of neptunium has a weight of 235.044 063 3 u.

Neptunium-236

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Neptunium-236 has 143 neutrons and a half-life of 154,000 years. It can decay by the following methods:

  • Electron capture: the decay energy is 0.93 MeV and the decay product is uranium-236. This usually decays (with a half-life of 23 million years) to thorium-232.
  • Beta emission: the decay energy is 0.48 MeV and the decay product is plutonium-236. This usually decays (half-life 2.8 years) to uranium-232, which usually decays (half-life 69 years) to thorium-228, which decays in a few years to lead-208.
  • Alpha emission: the decay energy is 5.007 MeV and the decay product is protactinium-232. This decays with a half-life of 1.3 days to uranium-232.

This particular isotope of neptunium has a mass of 236.04657 u. It is a fissile material; it has an estimated critical mass of 6.79 kg (15.0 lb),[16] though precise experimental data is not available.[17]

236
Np
 is produced in small quantities via the (n,2n) and (γ,n) capture reactions of 237
Np
,[18] however, it is nearly impossible to separate in any significant quantities from its parent 237
Np
.[19] It is for this reason that despite its low critical mass and high neutron cross section, it has not been researched extensively as a nuclear fuel in weapons or reactors.[17] Nevertheless, 236
Np
 has been considered for use in mass spectrometry and as a radioactive tracer, because it decays predominantly by beta emission with a long half-life.[20] Several alternative production routes for this isotope have been investigated, namely those that reduce isotopic separation from 237
Np
 or the isomer 236m
Np
. The most favorable reactions to accumulate 236
Np
 were shown to be proton and deuteron irradiation of uranium-238.[20]

Neptunium-237

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Neptunium-237 decay scheme (simplified)

237
Np
 decays via the neptunium series, which terminates with thallium-205, which is stable, unlike most other actinides, which decay to stable isotopes of lead.

In 2002, 237
Np
 was shown to be capable of sustaining a chain reaction with fast neutrons, as in a nuclear weapon, with a critical mass of around 60 kg.[21] However, it has a low probability of fission on bombardment with thermal neutrons, which makes it unsuitable as a fuel for light water nuclear power plants (as opposed to fast reactor or accelerator-driven systems, for example).

Inventory in spent nuclear fuel

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237
Np
 is the only neptunium isotope produced in significant quantity in the nuclear fuel cycle, both by successive neutron capture by uranium-235 (which fissions most but not all of the time) and uranium-236, or (n,2n) reactions where a fast neutron occasionally knocks a neutron loose from uranium-238 or isotopes of plutonium. Over the long term, 237
Np
 also forms in spent nuclear fuel as the decay product of americium-241.

237
Np
 is considered to be one of the most mobile radionuclides at the site of the Yucca Mountain nuclear waste repository (Nevada) where oxidizing conditions prevail in the unsaturated zone of the volcanic tuff above the water table.

Raw material for 238
Pu production

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Main articles: Plutonium-238 and Radioisotope thermoelectric generator

When exposed to neutron bombardment 237
Np
 can capture a neutron, undergo beta decay, and become 238
Pu
, this product being useful as a thermal energy source in a radioisotope thermoelectric generator (RTG or RITEG) for the production of electricity and heat. The first type of thermoelectric generator SNAP (Systems for Nuclear Auxiliary Power) was developed and used by NASA in the 1960's and during the Apollo missions to power the instruments left on the Moon surface by the astronauts. Thermoelectric generators were also embarked on board of deep space probes such as for the Pioneer 10 and 11 missions, the Voyager program, the Cassini–Huygens mission, and New Horizons. They also deliver electrical and thermal power to the Mars Science Laboratory (Curiosity rover) and Mars 2020 mission (Perseverance rover) both exploring the cold surface of Mars. Curiosity and Perseverance rovers are both equipped with the last version of multi-mission RTG, a more efficient and standardized system dubbed MMRTG.

These applications are economically practical where photovoltaic power sources are weak or inconsistent due to probes being too far from the sun or rovers facing climate events that may obstruct sunlight for long periods (like Martian dust storms). Space probes and rovers also make use of the heat output of the generator to keep their instruments and internals warm.[22]

Shortage of 237
Np stockpiles

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The long half-life (T½ ~ 88 years) of 238
Pu
 and the absence of γ-radiation that could interfere with the operation of on-board electronic components, or irradiate people, makes it the radionuclide of choice for electric thermogenerators.

237
Np
 is therefore a key radionuclide for the production of 238
Pu
, which is essential for deep space probes requiring a reliable and long-lasting source of energy without maintenance.

Stockpiles of 238
Pu
 built up in the United States since the Manhattan Project, thanks to the Hanford nuclear complex (operating in Washington State from 1943 to 1977) and the development of atomic weapons, are now almost exhausted. The extraction and purification of sufficient new quantities of 237
Np
 from irradiated nuclear fuels is therefore necessary for the resumption of 238
Pu
 production in order to replenish the stocks needed for space exploration by robotic probes.

Neptunium-239

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Neptunium-239 has 146 neutrons and a half-life of 2.356 days. It is produced via β− decay of the short-lived uranium-239, and undergoes another β− decay to plutonium-239. This is the primary route for making plutonium, as 239U can be made by neutron capture in uranium-238.[23]

Uranium-237 and neptunium-239 are regarded as the leading hazardous radioisotopes in the first hour-to-week period following nuclear fallout from a nuclear detonation, with 239Np dominating "the spectrum for several days."[24][25]

References

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  1. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. ^ Peppard, D. F.; Mason, G. W.; Gray, P. R.; Mech, J. F. (1952). "Occurrence of the (4n + 1) series in nature" (PDF). Journal of the American Chemical Society. 74 (23): 6081–6084. doi:10.1021/ja01143a074.
  3. ^ a b Zhang, Z. Y.; Gan, Z. G.; Yang, H. B.; et al. (2019). "New isotope 220Np: Probing the robustness of the N = 126 shell closure in neptunium". Physical Review Letters. 122 (19): 192503. Bibcode:2019PhRvL.122s2503Z. doi:10.1103/PhysRevLett.122.192503. PMID 31144958. S2CID 169038981.
  4. ^ Wang, M.; Audi, G.; Kondev, F. G.; Huang, W. J.; Naimi, S.; Xu, X. (2017). "The AME2016 atomic mass evaluation (II). Tables, graphs, and references" (PDF). Chinese Physics C. 41 (3): 030003-1–030003-442. doi:10.1088/1674-1137/41/3/030003.
  5. ^ Yang, H; Ma, L; Zhang, Z; Yang, C; Gan, Z; Zhang, M; et al. (2018). "Alpha decay properties of the semi-magic nucleus 219Np". Physics Letters B. 777: 212–216. Bibcode:2018PhLB..777..212Y. doi:10.1016/j.physletb.2017.12.017.
  6. ^ Ma, L.; Zhang, Z. Y.; Gan, Z. G.; et al. (2020). "Short-Lived α-emitting isotope 222Np and the Stability of the N=126 Magic Shell". Physical Review Letters. 125 (3): 032502. Bibcode:2020PhRvL.125c2502M. doi:10.1103/PhysRevLett.125.032502. PMID 32745401. S2CID 220965400.
  7. ^ Sun, M. D.; et al. (2017). "New short-lived isotope 223Np and the absence of the Z = 92 subshell closure near N = 126". Physics Letters B. 771: 303–308. Bibcode:2017PhLB..771..303S. doi:10.1016/j.physletb.2017.03.074.
  8. ^ Huang, T. H.; et al. (2018). "Identification of the new isotope 224Np" (pdf). Physical Review C. 98 (4): 044302. Bibcode:2018PhRvC..98d4302H. doi:10.1103/PhysRevC.98.044302. S2CID 125251822.
  9. ^ Asai, M.; Suekawa, Y.; Higashi, M.; et al. Discovery of 234 Np isomer and its decay properties (PDF) (Report) (in Japanese).
  10. ^ a b Niwase, T.; Watanabe, Y. X.; Hirayama, Y.; et al. (2023). "Discovery of New Isotope 241U and Systematic High-Precision Atomic Mass Measurements of Neutron-Rich Pa-Pu Nuclei Produced via Multinucleon Transfer Reactions" (PDF). Physical Review Letters. 130 (13): 132502-1–132502-6. doi:10.1103/PhysRevLett.130.132502. PMID 37067317. S2CID 257976576.
  11. ^ Plus radium (element 88). While actually a sub-actinide, it immediately precedes actinium (89) and follows a three-element gap of instability after polonium (84) where no nuclides have half-lives of at least four years (the longest-lived nuclide in the gap is radon-222 with a half life of less than four days). Radium's longest lived isotope, at 1,600 years, thus merits the element's inclusion here.
  12. ^ Specifically from thermal neutron fission of uranium-235, e.g. in a typical nuclear reactor.
  13. ^ Milsted, J.; Friedman, A. M.; Stevens, C. M. (1965). "The alpha half-life of berkelium-247; a new long-lived isomer of berkelium-248". Nuclear Physics. 71 (2): 299. Bibcode:1965NucPh..71..299M. doi:10.1016/0029-5582(65)90719-4.
    "The isotopic analyses disclosed a species of mass 248 in constant abundance in three samples analysed over a period of about 10 months. This was ascribed to an isomer of Bk248 with a half-life greater than 9 [years]. No growth of Cf248 was detected, and a lower limit for the β− half-life can be set at about 104 [years]. No alpha activity attributable to the new isomer has been detected; the alpha half-life is probably greater than 300 [years]."
  14. ^ This is the heaviest nuclide with a half-life of at least four years before the "sea of instability".
  15. ^ Excluding those "classically stable" nuclides with half-lives significantly in excess of 232Th; e.g., while 113mCd has a half-life of only fourteen years, that of 113Cd is eight quadrillion years.
  16. ^ Final Report, Evaluation of nuclear criticality safety data and limits for actinides in transport (PDF) (Report). Republic of France, Institut de Radioprotection et de Sûreté Nucléaire, Département de Prévention et d'étude des Accidents. Archived from the original (PDF) on 2011-05-19.
  17. ^ a b Reed, B. C. (2017). "An examination of the potential fission-bomb weaponizability of nuclides other than 235U and 239Pu". American Journal of Physics. 85: 38–44. doi:10.1119/1.4966630.
  18. ^ Analysis of the Reuse of Uranium Recovered from the Reprocessing of Commercial LWR Spent Fuel, United States Department of Energy, Oak Ridge National Laboratory.
  19. ^ **Jukka Lehto; Xiaolin Hou (2011). "15.15: Neptunium". Chemistry and Analysis of Radionuclides (1st ed.). John Wiley & Sons. 231. ISBN 978-3527633029.
  20. ^ a b Jerome, S.M.; Ivanov, P.; Larijani, C.; Parker, D.J.; Regan, P.H. (2014). "The production of Neptunium-236g". Journal of Environmental Radioactivity. 138: 315–322. doi:10.1016/j.jenvrad.2014.02.029. PMID 24731718.
  21. ^ P. Weiss (26 October 2002). "Neptunium Nukes? Little-studied metal goes critical". Science News. 162 (17): 259. doi:10.2307/4014034. JSTOR 4014034. Archived from the original on 26 May 2024. Retrieved 7 November 2013.
  22. ^ Witze, Alexandra (2014-11-27). "Nuclear power: Desperately seeking plutonium". Nature. 515 (7528): 484–486. Bibcode:2014Natur.515..484W. doi:10.1038/515484a. PMID 25428482.
  23. ^ "Periodic Table Of Elements: LANL - Neptunium". Los Alamos National Laboratory. Retrieved 2013-10-13.
  24. ^ [Film Badge Dosimetry in Atmospheric Nuclear Tests, By Committee on Film Badge Dosimetry in Atmospheric Nuclear Tests, Commission on Engineering and Technical Systems, Division on Engineering and Physical Sciences, National Research Council. pg24-35]
  25. ^ Bounding Analysis of Effects of Fractionation of Radionuclides in Fallout on Estimation of Doses to Atomic Veterans DTRA-TR-07-5. 2007
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